C14 is the smallest n, such that the value of the busy beaver number BB(n) is undecidable in ZFC (or equivalently ZF). Explicitly, it is the smallest n such that there is a Turing machine with n states for which it cannot be proven in ZFC (assuming ZFC is consistent) whether it halts or not.
The existence of C14 essentially follows from Gödel's second incompleteness theorem and the fact that Turing machines are strong enough to encode ZF.